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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク allylpalladium chloride dimer ： ウィキペディア英語版 allylpalladium chloride dimer |Section2= |Section7= |Section8= }} Allylpalladium(II) chloride dimer is a chemical compound with the formula (η3- C3H5)2Pd2Cl2. This yellow air-stable compound is an important catalyst used in organic synthesis.〔Tatsuno, Y.; Yoshida, T.; Otsuka, S. "(η3-allyl)palladium(II) Complexes" Inorganic Syntheses, 1990, volume 28, pages 342-345. ISBN 0-471-52619-3〕 ==Synthesis and reactions== The compound is prepared by purging carbon monoxide through a methanolic aqueous solution of palladium(II) chloride, sodium chloride, and allyl chloride.〔 :2Na2PdCl4 + 2 CH2=CHCH2Cl + 2 CO + 2 H2O → (C3H5)2Pd2Cl2 + 4 NaCl + 2 CO2 + 4 HCl APC reacts with sources of cyclopentadienyl anion to give the corresponding 18e complex cyclopentadienyl allyl palladium: :(C3H5)2Pd2Cl2 + 2 NaC5H5 → 2 Pd(η3-C3H5)(η5-C5H5) + 2 NaCl 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「allylpalladium chloride dimer」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.